On a small plate, add yellow sugar. Wet the rim of a glass with simple syrup (or lemon juice) and gently dab the top the glass in the yellow sugar, coating the rim. See above video for example. Set glass aside.
Combine vodka, limoncello, sweet and sour mix, lemon juice, and sugar in a cocktail shaker filled with ice. Shake until sugar is dissolved.
Pour into prepared martini glass. Garnish with a floating slice of lemon.
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